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Arbeláez Pérez, Oscar Felipe Villa Holguín, Aida Luz Becerra, Jaime Andres 37 2021-02-18T20:08:04Z 2021-02-18T20:08:04Z 2020-01 2020-04-26 1678-4383 https://doi.org/10.1007/s43153-020-00013-1 https://hdl.handle.net/20.500.12494/33440 Becerra, J. A., Arbeláez, Ó. F. y Villa, A. L. (2020). Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts. Brazilian Journal of Chemical Engineering, 37(1), 1–62. http://doi.org/10.1007/s43153-020-00013-1 El oro es un metal precioso muy inerte y resistente a la oxidación del aire en comparación con otros debido a su alto potencial de electrodo, primera energía de ionización y fuerte unión metálica. Sin embargo, cuando el oro se dispersa en forma de nanopartículas en diferentes soportes, alcanza propiedades catalíticas excepcionales, lo que promueve el desarrollo de materiales a base de oro catalíticamente activos en reacciones orgánicas. La principal ventaja de los procesos catalíticos heterogéneos frente a los homogéneos es la fácil separación del catalizador facilitando la recuperación, reciclaje y reducción de la cantidad de subproductos. Algunos catalizadores de oro heterogéneos tienen actividad en las transformaciones de monoterpenos y monoterpenoides, compuestos orgánicos naturales extraídos de plantas cuyas transformaciones producen sustancias con aplicaciones en química fina, farmacéutica, cosmética, agricultura, polímeros e industrias alimentarias. Esta revisión describe los logros de algunas transformaciones de monoterpenos y monoterpenoides informadas de 2002 a 2018 mediante oxidación, hidrogenación, isomerización y aminación sobre catalizadores heterogéneos a base de oro. Gold is a precious metal very inert and resistant to air oxidation compared with others due to its high electrode potential, first ionization energy and strong metallic bonding. However, when gold is dispersed as nanoparticles onto different supports it attains exceptional catalytic properties, promoting the development of gold-based materials catalytically active in organic reactions. The main advantage of heterogeneous catalytic processes against the homogeneous ones is the easy separation of catalyst facilitating recovering, recycling and reducing the amount of byproducts. Some heterogeneous gold catalysts have activity in the transformations of monoterpenes and monoterpenoids, natural organic compounds extracted from plants whose transformations produce substances with applications in fine chemicals, pharmaceuticals, cosmetics, agriculture, polymers and food industries. 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Catalysis Today 164(1):28–33 Oro, Monoterpenos Catalizadores Heterogeneos, Oxidación Isomerización Hidrogeación Aminación Gold monoterpenes heterogeneous catalysts oxidation isomerization hydrogenation amination Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts Artículo http://purl.org/coar/resource_type/c_6501 http://purl.org/coar/version/c_970fb48d4fbd8a85 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Atribución info:eu-repo/semantics/closedAccess http://purl.org/coar/access_right/c_14cb Publicationmetadata.only