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https://repository.ucc.edu.co/handle/20.500.12494/41541| Title: | Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures |
| Author: | Delgado, Daniel Ricardo Mogollon Waltero, Edgar Mauricio Ortiz C.P. Peña M.Á. Almanza O.A. Martínez F. Jouyban A. |
| Email autor: | danielr.delgado@campusucc.edu.co |
| Issue Date: | 2018 |
| Keywords: | Dissolution Enthalpy Entropy Solubility 1 ,4-Dioxane Dissolution mechanism Enthalpy-entropy compensation Equilibrium solubilities Jouyban-Acree model Thermodynamic quantities Triclocarban Van't Hoff equation Mixtures |
| Abstract: | The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of cosolvency models including the Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition. © 2018 Elsevier B.V. |
| Publisher: | Elsevier |
| metadata.dc.type: | Artículo |
| Citation: | Delgado DR,Mogollon EM,Ortiz CP,Peña MÁ,Almanza OA,Martínez F,Jouyban A. Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures. J MOL LIQ. 2018. 271. p. 522-529. . |
| Other Identifiers: | https://doi.org/10.1080/00319104.2013.842474 https://revia.areandina.edu.co/index.php/IA/article/view/945 |
| Appears in Collections: | Artículos Científicos |
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