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Title: Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
Author: Delgado D.R.
Mogollon-Waltero E.M.
Ortiz C.P.
Peña M.Á.
Almanza O.A.
Martínez F.
Jouyban A.
Keywords: Dissolution; Enthalpy; Entropy; Solubility; 1 ,4-Dioxane; Dissolution mechanism; Enthalpy-entropy compensation; Equilibrium solubilities; Jouyban-Acree model; Thermodynamic quantities; Triclocarban; Van't Hoff equation; Mixtures
Resume: The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of cosolvency models including the Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition. © 2018 Elsevier B.V.
Type: info:eu-repo/semantics/article
Other Identifiers:
Full text: J MOL LIQ
ISSN: 01677322
Appears in Collections:Artículos Científicos

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