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http://hdl.handle.net/20.500.12494/28676
| Title: | Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures |
| Author: | Delgado D.R. Mogollon-Waltero E.M. Ortiz C.P. Peña M.Á. Almanza O.A. Martínez F. Jouyban A. |
| Keywords: | Dissolution; Enthalpy; Entropy; Solubility; 1 ,4-Dioxane; Dissolution mechanism; Enthalpy-entropy compensation; Equilibrium solubilities; Jouyban-Acree model; Thermodynamic quantities; Triclocarban; Van't Hoff equation; Mixtures |
| Resume: | The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of cosolvency models including the Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition. © 2018 Elsevier B.V. |
| Type: | info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
| Other Identifiers: | https://ucc.fundanetsuite.com/Publicaciones/ProdCientif/PublicacionFrw.aspx?id=5837 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85053028646&doi=10.1016%2fj.molliq.2018.09.026&partnerID=40&md5=9a5e815f52257c540d4ce0c9423a0b37 |
| metadata.dc.rights: | https://v2.sherpa.ac.uk/id/publication/issn/0167-7322 |
| Full text: | J MOL LIQ ISSN: 01677322 |
| Appears in Collections: | Artículos Científicos |
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