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Title: Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
Author: Gaviria Castillo, Ana Carolina
Artunduaga Tole, Jesús Daniel
Rodríguez Rubiano, Juan Diego
Zuñiga Andrade, Jairo Alberto
Delgado, Daniel Ricardo
Jouyban, Abolghasem
Martínez, Fleming
Email autor: ana.gaviriaca@campusucc.edu.co
jesus.artunduagat@campusucc.edu.co
danielr.delgado@campusucc.edu.co
fmartinezr@unal.edu.co
Issue Date: 2017
Keywords: Triclocarban
{14-dioxane (1) + water (2)} mixtures
Solubility
Jouyban-acree model
Preferential solvation
Ikbi
Abstract: The equilibrium solubility and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K was reported. Mole fraction solubility varies continuously from 2.85 × 10–9 in neat water to 2.39 × 10–3 in neat 1,4-dioxane. Solubility behaviour was adequately correlated by means of the Jouyban-Acree model. Based on the inverse Kirkwood-Buff integrals, preferential solvation parameters were calculated. Triclocarban is preferentially solvated by water in water-rich mixtures (0.00 < x1 < 0.18) and also in 1,4-dioxane-rich mixtures (0.78 < x1 < 1.00) but preferentially solvated by 1,4-dioxane in mixtures with similar solvent compositions.
Program: Ingeniería Industrial
Headquarters: Neiva
Publisher: Universidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Industrial, Neiva
Type: Artículo
CC Licence: Licencia CC
Citation: Gaviria, A. C., Artunduaga, J. D., Rodríguez, J. D., Zuñiga, J. A., Delgado, D. R., Jouyban, A., & Martínez, F. (2017). Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K. Physics and Chemistry of Liquids, 1–12. https://doi.org/10.1080/00319104.2017.1416613
Resource reference: https://doi.org/10.1080/00319104.2017.1416613
Appears in Collections:Ingeniería Industrial

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